Call it synergy at work. Olivia Munn — who appears on the NBC mid-season comedy Perfect Couples — is set to guest star on the season premiere of NBC’ s Chuck on Sept. 20. Jezebel’s favorite Daily Show correspondent will reportedly play a CIA agent who intimidates Chuck and his sidekick, Morgan. Look out for many gratuitous shots of hair-tossing in slow motion. [ EW ]
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Olivia Munn to Get Chuck-ed