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A new process that simultaneously combines the light and heat of solar radiation to generate electricity could offer more than double the efficiency of existing solar cell technology, say the Stanford engineers who discovered it and proved that it works. The process, called “photon enhanced thermionic emission,” or PETE, could reduce the costs of solar energy production enough for it to compete with oil as an energy source. Stanford engineers have figured out how to simultaneously use the light and heat of the sun to generate electricity in a way that could make solar power production more than twice as efficient as existing methods and potentially cheap enough to compete with oil. Unlike photovoltaic technology currently used in solar panels – which becomes less efficient as the temperature rises – the new process excels at higher temperatures. Called “photon enhanced thermionic emission,” or PETE, the process promises to surpass the efficiency of existing photovoltaic and thermal conversion technologies. “This is really a conceptual breakthrough, a new energy conversion process, not just a new material or a slightly different tweak,” said Nick Melosh, an assistant professor of materials science and engineering, who led the research group. “It is actually something fundamentally different about how you can harvest energy.” And the materials needed to build a device to make the process work are cheap and easily available, meaning the power that comes from it will be affordable. Melosh is senior author of a paper describing the tests the researchers conducted. It was published online Aug. 1 in Nature Materials. “Just demonstrating that the process worked was a big deal,” Melosh said. “And we showed this physical mechanism does exist; it works as advertised.” Most photovoltaic cells, such as those used in rooftop solar panels, use the semiconducting material silicon to convert the energy from photons of light to electricity. But the cells can only use a portion of the light spectrum, with the rest just generating heat. This heat from unused sunlight and inefficiencies in the cells themselves account for a loss of more than 50 percent of the initial solar energy reaching the cell. If this wasted heat energy could somehow be harvested, solar cells could be much more efficient. The problem has been that high temperatures are necessary to power heat-based conversion systems, yet solar cell efficiency rapidly decreases at higher temperatures. Until now, no one had come up with a way to wed thermal and solar cell conversion technologies. Melosh's group figured out that by coating a piece of semiconducting material with a thin layer of the metal cesium, it made the material able to use both light and heat to generate electricity. “What we've demonstrated is a new physical process that is not based on standard photovoltaic mechanisms, but can give you a photovoltaic-like response at very high temperatures,” Melosh said. “In fact, it works better at higher temperatures. The higher the better.” While most silicon solar cells have been rendered inert by the time the temperature reaches 100 degrees Celsius, the PETE device doesn't hit peak efficiency until it is well over 200 C. Because PETE performs best at temperatures well in excess of what a rooftop solar panel would reach, the devices will work best in solar concentrators such as parabolic dishes, which can get as hot as 800 C. Dishes are used in large solar farms similar to those proposed for the Mojave Desert in Southern California and usually include a thermal conversion mechanism as part of their design, which offers another opportunity for PETE to help generate electricity as well as minimize costs by meshing with existing technology. “The light would come in and hit our PETE device first, where we would take advantage of both the incident light and the heat that it produces, and then we would dump the waste heat to their existing thermal conversion systems,” Melosh said. “So the PETE process has two really big benefits in energy production over normal technology.” Photovoltaic systems never get hot enough for their waste heat to be useful in thermal energy conversion, but the high temperatures at which PETE performs are perfect for generating usable high-temperature waste heat. Melosh calculates the PETE process can get to 50 percent efficiency or more under solar concentration, but if combined with a thermal conversion cycle, could reach 55 or even 60 percent – almost triple the efficiency of existing systems. The team would like to design the devices so they could be easily bolted on to existing systems, thereby making conversion relatively inexpensive. added by: JanforGore